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why do orbitals hybridise????

why do orbitals hybridise????

Grade:11

1 Answers

Hasan Ali
35 Points
12 years ago

Dear shreya k

 

In chemistry, hybridisation (or hybridization) is the concept of mixing atomic orbitals to form new hybrid orbitals suitable for the qualitative description of atomic bonding properties. Hybridised orbitals are very useful in the explanation of the shape of molecular orbitals for molecules. It is an integral part of valence bond theory. Although sometimes taught together with the valence shell electron-pair repulsion (VSEPR) theory, valence bond and hybridization are in fact not related to the VSEPR model. Hybridisation theory is not as practical for quantitative calculations as molecular orbital theory. Problems with hybridisation are especially notable when the d orbitals are involved in bonding, as in coordination chemistry and organometallic chemistry. Although hybridisation schemes in transition metal chemistry can be used, they are not generally as accurate.

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