does CO2 react with PCl5 to give POCl3??????
does CO2 react with PCl5 to give POCl3??????
samir ranjan , 14 Years ago
Grade
Inorganic Chemistry> IIT 2011...
3 Answers
somil garg
no
Approved Last Activity: 14 Years ago
samir ranjan
is it????somil bhaiya?????r u 100% sure??
Shrinivas
Phosgene is very unstable, and the C=O bond is quite strong, so the rxn doesn`t take place. In SO2, the S=O bond is quite weak, as the overlapping won`t be effective , as the sulphur is very big in size. So, the reaction sulphur dioxide + phosphorus pentachloride -----> POCl3+SOCl2 is possible.
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