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Dear Anshu ,
Electropositivity is a measure of an element's ability to accept electrons.
Electrode reduction potential is the measure of that material 's ability to get reduced but expresses in volts .similar is for oxidation potential , it is the measure of ability of oxidation of the elemnent .
The difference is nothing. Each is just expressed ina different format as per the requirement of that application. Electronegativity is expresses as a number , whereas potential as volts .
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