Grade 12th passIIT JEE Entrance Exam
Does intramolecular hydrogen bonding affect boiling point?
Does intramolecular hydrogen bonding affect boiling point?
1 Answer
Vikas TU
Para-nitrophenol shows intermolecular hydrogen bonding, which causes an increase in boiling point as different molecules bond better with each other, as compared to ortho-nitrophenol, where there is intramolecular hydrogen bonding, which does not help in increasing the boiling point, hence p-nitrophenol has a higher boiling point than o-nitrophenol.
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