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Grade: 12

                        

An octahedral complex with molecular composition M.5NH3.Cl.SO4 has two isomers A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCl2 solution.The type of isomer exhibited by the complex is: 1)Coordinate 2)Geometrical 3)Ionisation 4)Linkage

6 years ago

Answers : (1)

Aditya Sharma
24 Points
							i think it should be option 3) Ionisation
Because white ppt of AgCl if formed when Chloride reacts as an anion and  not in the coordiantion sphere.
and white ppt of BaSO4 if formed when SO4(2-)  is anion and not in the coordiantion sphere.
						
6 years ago
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