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Ortho–Nitrophenol is less soluble in water than p– and m– Nitrophenols because : (1) o–Nitrophenol is more volatile in steam than those of m – and p–isomers (2) o–Nitrophenol shows Intramolecular H–bonding (3) o–Nitrophenol shows Intermolecular H–bonding (4) Melting point of o–Nitrophenol is lower than those of m–and p–isomers.

Ortho–Nitrophenol is less soluble in water than p– and m– Nitrophenols because :
(1) o–Nitrophenol is more volatile in steam than those of m – and p–isomers
(2) o–Nitrophenol shows Intramolecular H–bonding
(3) o–Nitrophenol shows Intermolecular H–bonding
(4) Melting point of o–Nitrophenol is lower than those of m–and p–isomers.

Grade:12

1 Answers

Avinash
askIITians Faculty 1241 Points
8 years ago
(2) o–Nitrophenol shows Intramolecular H–bonding

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