Charge Q is given to metal plate of surface area A. It gets equally divided on the total surface, both sides. As such surface charge density on each side is
σ=Q/2A
When the plates are brought close at a distance between the two d, its capacitance
C=εr ε0 A/d
where εr is the dielectric constant of the material between the plates (for vacuum, εr =1) and ε0 is the electric constant.
In our case
C=ε0 A/d
We know that electric field due to surface charge distribution σ on a conductor is given by
E =σ/ε0 r
where r is unit vector perpendicular to the conductor's surface.
Since both charges are of same kind net electric field between the plates is difference of two fields.
E1-E2 = (σ1/ε0 -σ2/ε0) r ….(1)
Here r is unit vector defined by r1- r2
Electric field between parallel plates is also given as
E=V/d r …..(2)
where V is potential difference between the two plates
Comparing (1) and (2) we get
V/d=(Q1-Q2)/(2Aε0)
or V=(Q1-Q2)d/(2Aε0)
Using value of C we get
V=(Q1−Q2)/2C