Brother,
emf is the potential difference of entire circuit. I.e. internet resistance of battery is also consider while calculating the emf.
emf is given by:-
E=I/(R+r) where R is externel resistance , r is internet resistance of battery.
Voltage is the potential difference between two terminals of battery. I.e. internet resistance of battery will not considered while calculating voltage.
Voltage is given by:-
V=I/R