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Is there any change in the composition of ntc and ptc thermistors?

Is there any change in the composition of ntc and ptc thermistors?

Grade:12th pass

1 Answers

Arun
25750 Points
6 years ago
Dear student

Many NTC thermistors are made from a pressed disc, rod, plate, bead or cast chip of semiconducting material such as sintered metal oxides. They work because raising the temperature of a semiconductor increases the number of active charge carriers - it promotes them into the conduction band. The more charge carriers that are available, the more current a material can conduct. In certain materials like ferric oxide (Fe2O3) with titanium (Ti) doping an n-type semiconductor is formed and the charge carriers are electrons. In materials such as nickel oxide (NiO) with lithium (Li) doping a p-type semiconductor is created where holes are the charge carriers.
 
Most PTC thermistors are made from doped polycrystalline ceramic (containing barium titanate (BaTiO3) and other compounds) which have the property that their resistance rises suddenly at a certain critical temperature. Barium titanate is ferroelectric and its dielectric constant varies with temperature. Below the Curie point temperature, the high dielectric constant prevents the formation of potential barriers between the crystal grains, leading to a low resistance. In this region the device has a small negative temperature coefficient. At the Curie point temperature, the dielectric constant drops sufficiently to allow the formation of potential barriers at the grain boundaries, and the resistance increases sharply with temperature. At even higher temperatures, the material reverts to NTC behaviour
 
Regards
Arun (askIITians forum expert)

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