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in gaseous state , basic character of amine is tertiary>sec.>primary amine>ammonia but there is no possible to donate electron from nitrogen in gasous phase .and 1 question more . in aqu. solution , secondary>tertiary>primary amine>ammonia why secondary amine is more basic in aq. sol. and actual basicity order of methyl and ethylamine is as under: 1- (CH3)2NH>CH3NH2>(CH3)3N>NH3 2- (CH3CH2)2NH> (CH3CH2)3N>( CH3CH2 )NH2>NH3 BUT IN THESE 2 CASES DIFFERENT IN ( -NH2 , -N ) WHY GIVE ME DETAIL WITH DIAGRAM

in gaseous state , basic character of amine is tertiary>sec.>primary amine>ammonia but there is no possible to donate electron from nitrogen in gasous phase .and 1 question more .


in aqu. solution , secondary>tertiary>primary amine>ammonia 


why secondary amine is more basic in aq. sol.


and 


actual basicity order of methyl and ethylamine is as under:


1- (CH3)2NH>CH3NH2>(CH3)3N>NH3


2- (CH3CH2)2NH> (CH3CH2)3N>( CH3CH2 )NH2>NH3


BUT IN THESE 2 CASES DIFFERENT IN  (  -NH2 , -N  ) WHY GIVE ME DETAIL WITH DIAGRAM

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