Micelle formation occurs when soap or other surfactants are added to water due to the unique structure and properties of soap molecules. Soap molecules are typically composed of a hydrophilic (water-attracting) "head" and a hydrophobic (water-repelling) "tail." This molecular structure allows soap molecules to interact with both water and nonpolar substances like oils and grease.
Here's why micelle formation takes place in water:
Hydrophilic Head: The hydrophilic head of soap molecules is attracted to water molecules because of their polar nature. The hydrophilic head contains charged or polar groups that can form hydrogen bonds with water molecules.
Hydrophobic Tail: The hydrophobic tail of soap molecules is repelled by water because it is nonpolar and cannot form favorable interactions with water molecules. Instead, the hydrophobic tails prefer to interact with other nonpolar substances, such as oil or grease.
When soap is added to water containing nonpolar substances like oil or grease, the soap molecules self-assemble into structures called micelles. In a micelle:
The hydrophilic heads of soap molecules point outward, forming the outer shell of the micelle. These heads are in contact with water and can interact with water molecules.
The hydrophobic tails of soap molecules cluster together in the center of the micelle, away from water. This arrangement shields the hydrophobic tails from water and keeps them surrounded by other hydrophobic tails.
The micelles effectively trap the nonpolar substances (e.g., oil or grease) in their hydrophobic cores while allowing the hydrophilic heads to interact with the surrounding water. This makes it easier to disperse and emulsify nonpolar substances in water, allowing them to be washed away.
Regarding your question about other solvents like ethanol, micelle formation is less likely to occur in solvents like ethanol because ethanol is a polar solvent. Polar solvents, like water, tend to disrupt the formation of micelles because they can solvate both the hydrophilic heads and the hydrophobic tails of soap molecules to some extent. Soap molecules are more likely to remain individually dispersed in polar solvents like ethanol, rather than forming micelles. In nonpolar solvents, such as hydrocarbon-based solvents, micelle formation can occur if the solvent is immiscible with water and the soap molecules can aggregate to minimize their exposure to the polar solvent. However, the stability and size of micelles may vary depending on the specific solvent and conditions.