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12 grade chemistry others

Which one of the following is aromatic? (A) Cyclopentadienyl cation (B) Cyclooctatetraene (C) Cycloheptatriene (D) Cycloheptatrienyl cation

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1 Year agoGrade
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1 Year ago

Among the options provided, the compound that is aromatic is (A) Cyclopentadienyl cation.

Aromaticity refers to a property of cyclic, planar compounds that possess a specific pattern of alternating single and double bonds, known as a conjugated system, and fulfill the following criteria:

The molecule must be cyclic.
It must be planar or nearly planar.
It must possess a continuous loop of overlapping p-orbitals.
It must have a total of (4n + 2) π electrons, where "n" is a non-negative integer.
The Cyclopentadienyl cation (C₅H₅⁺) satisfies all these criteria. It has a cyclic structure, is planar, possesses a continuous loop of overlapping p-orbitals, and has 6 π electrons [(4n + 2) with n = 1]. Therefore, the Cyclopentadienyl cation is considered aromatic.