The reaction of C₆H₅CH₂Br (benzyl bromide) with aqueous sodium hydroxide primarily follows the SN2 mechanism. This is because the benzyl group is a good leaving group, and the reaction occurs in a polar protic solvent, which favors bimolecular nucleophilic substitution.
Key Points to Consider
- SN2 Mechanism: This involves a single concerted step where the nucleophile attacks the substrate while the leaving group departs.
- Temperature Influence: While temperature can affect reaction rates, the SN2 pathway is generally favored for this substrate under standard conditions.
- Saytzeff Rule: This rule pertains to elimination reactions and is not directly applicable here since we are discussing substitution.
Therefore, the correct answer is A. SN2 mechanism.