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How to convert benzene into chlorobenzene?

Aniket Singh , 11 Months ago
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Askiitians Tutor Team

To convert benzene into chlorobenzene, you can use a chemical reaction known as electrophilic substitution. This process involves the substitution of a hydrogen atom in benzene with a chlorine atom. Here's a common method to convert benzene into chlorobenzene:

Start with benzene (C₆H₆) and chlorine gas (Cl₂).

Create a reaction mixture by combining benzene and a suitable solvent such as chloroform (CHCl₃) or carbon tetrachloride (CCl₄) in a reaction vessel. The solvent helps dissolve the reactants and acts as a medium for the reaction.

Add an iron(III) chloride (FeCl₃) catalyst to the reaction mixture. The catalyst helps facilitate the reaction.

Carefully introduce chlorine gas into the reaction mixture. The chlorine gas will act as the source of chlorine atoms for substitution.

Heat the reaction mixture to around 50-60°C. The heat provides the necessary energy to initiate the reaction.

Allow the reaction to proceed for a specific period of time, typically a few hours, while maintaining the temperature.

After the reaction is complete, cool the reaction mixture and carefully separate the organic layer (containing chlorobenzene) from the aqueous layer.

Wash the organic layer with water to remove any impurities and residual reactants.

Dry the organic layer by using anhydrous sodium sulfate (Na₂SO₄) or a similar drying agent. The drying agent helps remove any remaining water from the organic layer.

Finally, distill the chlorobenzene to purify it further if desired.

It's important to note that this process should be conducted with caution and under proper laboratory conditions due to the hazardous nature of the reactants involved. It is advisable to consult a qualified chemist or perform this reaction in a professional laboratory setting.





Last Activity: 11 Months ago
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