Metallic conduction and electrolytic conduction are two different mechanisms of electrical conduction. Here are two key differences between them:
Nature of Conductor:
In metallic conduction, electrical conduction occurs within metals or metallic materials. Metallic substances have a lattice structure of positively charged ions surrounded by a sea of delocalized electrons. These free electrons can move freely throughout the material, carrying electric charge and enabling conduction. In contrast, electrolytic conduction occurs in electrolytes, which are typically liquid or molten solutions containing ions. The ions in the electrolyte are responsible for carrying the electric charge.
Mechanism of Conduction:
In metallic conduction, the conduction of electrons takes place through the movement of free electrons. When an electric potential is applied across a metal, the free electrons drift in response to the electric field, creating an electric current. This process is facilitated by the delocalized nature of the electrons in the metallic lattice. On the other hand, electrolytic conduction involves the movement of charged ions in the electrolyte. When an electric potential is applied, positive ions move towards the negative electrode (cathode), while negative ions move towards the positive electrode (anode). This migration of ions constitutes the flow of electric current in the electrolyte.
These differences in the nature of the conductor and the mechanism of conduction lead to distinct properties and applications for metallic and electrolytic conduction. Metallic conduction is prevalent in metallic wires and is responsible for electrical conduction in most solid conductors, while electrolytic conduction is commonly observed in electrolytic cells, electroplating processes, and certain types of batteries.