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Distinguish between hexagonal close packing and cubic close packing.

Aniket Singh , 1 Year ago
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Askiitians Tutor Team

Hexagonal close packing (HCP) and cubic close packing (CCP) are two different arrangements of atoms or spheres that maximize packing efficiency in crystalline structures. Here are the main distinctions between the two:

Arrangement of Layers:

In hexagonal close packing (HCP), the layers of spheres or atoms are arranged in an ABAB... sequence, meaning that each sphere in a given layer is directly above or below the center of the triangle formed by three spheres in the layer below it.
In cubic close packing (CCP), the layers of spheres or atoms are arranged in an ABCABC... sequence, meaning that each sphere in a given layer occupies a position in the layer above that is not directly above or below the spheres in the layer below.
Unit Cell:

In HCP, the unit cell consists of three layers of spheres, with each sphere in the second and third layers positioned directly above the depressions formed by the spheres in the layer below, creating a hexagonal arrangement.
In CCP, the unit cell consists of four layers of spheres, with each sphere in the second and third layers positioned directly above the depressions formed by the spheres in the layer below, creating a cubic arrangement.
Coordination Number:

In HCP, each sphere is in contact with 12 others, with 6 in its own layer, 3 in the layer above, and 3 in the layer below.
In CCP, each sphere is in contact with 12 others, with 6 in its own layer, 3 in the layer above, and 3 in the layer below.
Density:

Both HCP and CCP have the same packing density, which is approximately 74% of the total volume filled with spheres or atoms.
Crystal Structure:

HCP crystal structure is commonly found in metals like magnesium and titanium.
CCP crystal structure is commonly found in metals like copper, silver, and gold.
In summary, while both HCP and CCP arrangements have similar packing efficiencies and coordination numbers, they differ in the arrangement of layers, unit cells, and crystal structures.

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