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12 grade chemistry others

2,4 DNP reacts with carbonyls (aldehydes/ketones) to give yellow ppt. This reaction is a dehydration type reaction as shown above. A mixture of benzaldehyde and formaldehyde is heated with 2,4DNP. How many organic products will be obtained after fractional distillation?

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1 Year agoGrade
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1 Answer

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1 Year ago

The reaction described involves the formation of a hydrazone by the reaction of a carbonyl compound (an aldehyde or a ketone) with 2,4-Dinitrophenylhydrazine (2,4-DNP). This is a classic test for the presence of carbonyl compounds, where a yellow or orange precipitate forms due to the formation of the hydrazone derivative.

Now let's break the problem down:

Reactants:

Benzaldehyde (C₆H₅CHO): An aromatic aldehyde.
Formaldehyde (HCHO): The simplest aldehyde.
Reaction of Each Aldehyde with 2,4-DNP:

When benzaldehyde reacts with 2,4-DNP, it will form a yellow precipitate, which is the 2,4-DNP derivative of benzaldehyde.
When formaldehyde reacts with 2,4-DNP, it will form another 2,4-DNP derivative of formaldehyde.
Dehydration Reaction: The reaction between the carbonyl group (C=O) of the aldehyde and 2,4-DNP leads to the elimination of water (dehydration) and the formation of a hydrazone derivative.

Fractional Distillation: Fractional distillation is used to separate compounds based on their boiling points. Since the products are different organic compounds with varying structures, they will have different boiling points.

Products:
In this case, there will be two organic products after fractional distillation:

2,4-DNP derivative of benzaldehyde
2,4-DNP derivative of formaldehyde
These two compounds will have different physical properties (such as boiling points), which allows them to be separated by fractional distillation.

Thus, the answer is: Two organic products will be obtained after fractional distillation.


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is Pradeep Chemistry+Ncert sufficient for all of the theory of Jee Mains Chemistry?


Hi, I’m a self-study JEE 2027 aspirant with a large 11th backlog. Since I don’t think 6–8 hour one-shots are sufficient to cover the full theory + breadth of problem types of a JEE chapter, I’ve shifted from lecture-based preparation to book-based self-study.


I have a problem with using NCERT as my primary chemistry source. In my experience, it is concise and information-heavy, but often lacks detailed explanations, systematic organisation of concepts, and categorisation of problem types. This seems especially problematic for Physical and Organic Chemistry, where I feel that simply reading NCERT may not give enough depth or problem-solving preparation.


So I’m considering this approach:


Pradeep Chemistry → complete the chapter thoroughly from Pradeep → then read NCERT for that chapter → solve JEE Main PYQs/problems.


My main question is:


Is Pradeep + NCERT sufficient as the complete theory source for JEE Main-level Chemistry?


In other words, after thoroughly completing a chapter from Pradeep and then NCERT, can I consider the theory part of that chapter complete for JEE Main, with only PYQs/problem practice remaining?


I’m asking specifically about JEE Main level, not Advanced.


Also, if Pradeep is not sufficient, what specific gap does it leave, and what would you recommend as a better book-based alternative for self-study?

Grade 1212 grade chemistry others
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