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11 grade chemistry others

What is the effective nuclear charge of 3d electrons in zinc?
A) 8.85
B) 6.25
C) 4.85
D) 12.25






Profile image of Aniket Singh
1 Year agoGrade
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1 Answer

Profile image of Askiitians Tutor Team
1 Year ago

The effective nuclear charge experienced by the 3d electrons in zinc can be calculated by considering the atomic number and electron configuration.

Zinc (Zn) has an atomic number of 30. Its electron configuration is:

1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰

The 3d electrons in zinc experience some shielding from the inner electrons, so the effective nuclear charge (Zeff) can be approximated using Slater's rules. According to Slater's rules, the effective nuclear charge experienced by the 3d electrons can be calculated as follows:

Zeff = Z - σ

Where:
Z is the atomic number (30 for zinc).
σ is the shielding constant.

For 3d electrons in zinc:
σ = 1s² (2) + 2s² (2) + 2p⁶ (6) + 3s² (2) + 3p⁶ (6) + 4s² (2) + 3d¹⁰ (10) = 30

So, Zeff = 30 - 30 = 0

However, this means that the effective nuclear charge experienced by the 3d electrons is essentially 0. Therefore, none of the provided options seem correct. Are you sure about the question or the answer choices?