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The correct statements among I to III regarding group 13 elements oxides are: (I) Boron trioxide is acidic. (II) Oxides of aluminium and gallium are amphoteric. (III) Oxides of indium and thallium are basic. (A) (I), (II) and (III) (B) II) and (III) only (C) (I) and (III) only (D) (I) and (II) only

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1 Year agoGrade
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1 Answer

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1 Year ago

To analyze the statements regarding group 13 elements' oxides, let's consider each one in detail:

### Statement I: Boron trioxide is acidic.
- **Explanation**: Boron trioxide (\( \text{B}_2\text{O}_3 \)) is indeed acidic. When it reacts with water, it forms boric acid (\( \text{H}_3\text{BO}_3 \)), which is a weak acid. Therefore, this statement is **true**.

### Statement II: Oxides of aluminium and gallium are amphoteric.
- **Explanation**: Aluminium oxide (\( \text{Al}_2\text{O}_3 \)) and gallium oxide (\( \text{Ga}_2\text{O}_3 \)) are both amphoteric. They can react with both acids and bases. For instance, \( \text{Al}_2\text{O}_3 \) can react with hydrochloric acid (\( \text{HCl} \)) to form aluminium chloride (\( \text{AlCl}_3 \)), and with sodium hydroxide (\( \text{NaOH} \)) to form sodium aluminate. Therefore, this statement is also **true**.

### Statement III: Oxides of indium and thallium are basic.
- **Explanation**: Indium oxide (\( \text{In}_2\text{O}_3 \)) tends to be amphoteric, not strictly basic. Thallium oxide (\( \text{Tl}_2\text{O}_3 \)) is generally considered more basic but can also show amphoteric behavior. Therefore, this statement is **partially true**, but not entirely accurate, as it does not cover the full nature of both oxides.

### Conclusion
- Statement I is **true**.
- Statement II is **true**.
- Statement III is **false** in its strong assertion that both oxides are basic.

Thus, the correct answer is **(D) (I) and (II) only**.