Valence Electrons:
Valence electrons are the electrons found in the outermost shell (valence shell) of an atom. These electrons are responsible for the chemical properties of an element because they are involved in the formation of chemical bonds. The valence shell is the highest energy level of an atom and can hold a certain number of electrons, depending on the element's position in the periodic table.
For example, elements in the alkali metal group (Group 1) have one valence electron in their outermost shell, while elements in the alkaline earth metal group (Group 2) have two valence electrons. Elements in groups 13 to 18 have three to eight valence electrons, respectively.
The number of valence electrons an element has largely determines its reactivity and ability to form chemical bonds. Elements tend to gain, lose, or share electrons to achieve a stable electron configuration similar to that of a noble gas (Group 18 elements), which has a full valence shell.
Covalency:
Covalency refers to the number of covalent bonds that an atom can form with other atoms when it participates in a chemical compound. A covalent bond is formed when atoms share electrons to achieve a stable electron configuration. The number of covalent bonds an atom can form is directly related to its valence electrons.
For example, carbon (C) has four valence electrons (in group 14), so it can form up to four covalent bonds by sharing its valence electrons with other atoms. Oxygen (O) has six valence electrons (in group 16) and can form up to two covalent bonds. Hydrogen (H) has one valence electron (in group 1) and can form only one covalent bond.
Covalency plays a crucial role in the formation of molecules and compounds. Elements with higher covalency tend to form complex molecules with multiple bonds, while elements with lower covalency tend to form simpler molecules with fewer bonds.
In summary, the valence electrons are the electrons in the outermost shell of an atom, while covalency is the number of covalent bonds an atom can form based on the number of its valence electrons. Valence electrons dictate the chemical properties of an element, while covalency influences its ability to form chemical bonds and participate in the formation of compounds.