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Aldotetroses

If we examine the general formula of an aldotetrose, we see that they contain two asymmetric carbon atoms (marked by asterisks).
This means that 22 or 4 optical isomers are possible. They may be represented as the following two pairs:    

2235_carbohydrates.JPG

All four isomers have been prepared synthetically. The D- and L-erythrose are mirror images, that is, they are enantiomers. They have exactly the same degree of rotation but in  opposite directions. Equal amounts of the two would constitute a racemic mixture, that is, a mixture that would allow a plane-polarised light to pass through the solution unchanged but could be separated into detrorotatory and laevorotatory isomers. The same comments  hold for D- and L-threose. However, D-erythrose and L-threose are not images, that is, they are diastereomers (optical isomers that are not mirror images are called diastereomers), and the degree of rotation of each would probably differ.

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