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Please answer me the 48 th one and also state the reason....

Please answer me the 48th one and also state the reason....

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Grade:11

1 Answers

Vikas TU
14149 Points
7 years ago
The order should be:
I > IV > Ii > III
In first compound, -NO2 group has highest -M effect and then -SO3H.
and they are in absence of any – CH3 groups which reduces the -M or -I effect that’s why.
In II and III the -CH3 groups are showing +I effct and hence Inductive effect is distance dependent
those groups which are nearer to -NO2 would exibhit less acidity as -NO2 has higher -M effect than -SO3H.

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