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gOlU g3n|[0]uS Grade: Upto college level
        

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6 years ago

Answers : (1)

SAGAR SINGH - IIT DELHI
879 Points
										

DEAR GOLU,


One which is more acidic will have less PKa value...


So the order goes like:


1)CH3(NO2)>(NO2)2-CH2>(NO2)3-CH


 


2)m-nitrophenol > p-nitrophenol>2,4,6 trinitrophenol>phenol


 


3)(N02)-CH2-COOH>CH3-C0-CH2-COOH>CH3COOH


In orthonitrophenol the hydrogen of the -OH group satisfies the conditions for intramolecular hydrogen bonding and should in theory be bound to the nitrogen of the nitro substituent making difficult its loss as H+.







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Sagar Singh


B.Tech IIT Delhi







6 years ago
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