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WHY IS CCL3(-) MORE STABLE THAN CF3(-). ON THE BASIS OF REVERSE HYPERCONJUGATION ANSWER MUST BE OTHERWISEAND EVEN IDUCTIVE EFFECT STABLISES CF3(-) MORE. PLEASE EXPLAIN!!
Dear Nikhil,
Since Chlorine is more electronagative than Florine, there is more inductive effect on carbon of CCl3(-) than in CF3(-) which stablises its negative charge. The negative charge on the carbon in CCl3(-) is further stablised in the vacant d-orbital of Chlorine which is not possible in case of CF3(-).
Thank you.
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