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Although nitration usually causes elevation of B.P.yet the nitration of resorcinol to 2-nitroresorcinol decreases their B.P. then their parent compound . Explain?
Hi vaibhav,
due to intra molecular hydrogen bonding BP decrease....where as due to inter molecular hydrogen bonding BP increase....
even though nitration causes elevation in BP...the intra molecular hydrogen bonding formed between O of NO2 and H of -OH decrease the BP....
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